Nickel
Nickel is a chemical element with the symbol Ni and atomic
number 28. It is a silvery-white lustrous metal with a slight golden tinge.
Nickel belongs to the transition metals and is hard and ductile. Pure nickel,
powdered to maximize the reactive surface area, shows a significant chemical
activity, but larger pieces are slow to react with air under standard
conditions because an oxide layer forms on the surface and prevents further
corrosion (passivation). Even so, pure native nickel is found in Earth's crust
only in tiny amounts, usually in ultramafic rocks, and in the interiors of
larger nickel–iron meteorites that were not exposed to oxygen when outside
Earth's atmosphere. Meteoric nickel is found in combination with iron, a
reflection of the origin of those elements as major end products of supernova
nucleo synthesis. An iron–nickel mixture is thought to compose Earth's outer
and inner cores.
Major production sites include the Sudbury region in Canada
(which is thought to be of meteoric origin), New Caledonia in the Pacific, and
Norilsk in Russia.
Nickel is slowly oxidized by air at room temperature and is
considered corrosion-resistant. Historically, it has been used for plating iron
and brass, coating chemistry equipment, and manufacturing certain alloys that
retain a high silvery polish, such as German silver. About 9% of world nickel
production is still used for corrosion-resistant nickel plating. Nickel-plated
objects sometimes provoke nickel allergy. Nickel has been widely used in coins,
though its rising price has led to some replacement with cheaper metals in
recent years. Nickel is one of four elements (the others are iron, cobalt, and
gadolinium) that are ferromagnetic at approximately room temperature. Alnico
permanent magnets based partly on nickel are of intermediate strength between
iron-based permanent magnets and rare-earth magnets. The metal is valuable in
modern times chiefly in alloys; about 68% of world production is used in
stainless steel. A further 10% is used for nickel-based and copper-based
alloys, 7% for alloy steels, 3% in foundries, 9% in plating and 4% in other
applications, including the fast-growing battery sector. As a compound, nickel
has a number of niche chemical manufacturing uses, such as a catalyst for
hydrogenation, cathodes for batteries, pigments and metal surface treatments.
Nickel is an essential nutrient for some microorganisms and plants that have
enzymes with nickel as an active site.